High chromium contents in Tertiary coal deposits of northwestern Washington — A key to their depositional history

Chromium contents obtained from 20 coal and 5 associated rock samples collected from the basal part of the Eocene Chuckanut Formation, in Skagit and Whatcom counties, northwest Washington, range between 30 and 300 ppm (mean 120 ppm whole-coal basis). The lenticular coals, ranging in rank from subbituminous to anthracite, and with an ash content of 12–46%, crop out along the western flank of the Cascade Range. Results of X-ray diffraction analysis of low-temperature ash show that the mineral matter in the coal samples consists predominantly of quartz and clay (kaolinite, illite and chlorite group). However, accessory minerals, isolated from the coal samples and analyzed by X-ray diffraction, scanning electron microscope and optical methods, contain angular fragments and euhedral crystals of the spinel group (chromite, magnetite and trevorite ), kaolinite-serpentine group (antigorite and chrysotile), chlorite group, amphibole group and pyroxene group minerals (augite, diopside and enstatite), all of which are commonly enriched in chromium.Although associated primarily with the inorganic fraction of the coal, concentrations of chromium in the samples show no statistically significant correlation with ash content. Localized concentrations of chromium in the coal are the result of natural contamination from the alteration of detrital chromium-bearing mineral grains introduced into the peat-forming mires from nearby Jurassic ophiolite bodies. The coals formed in the early Eocene, in rapidly subsiding small basins that developed during the uplift and erosion of the pre-Tertiary ophiolite terrain. Scattered bodies of source rock, random distribution of chromium-bearing minerals within the coal and sample heterogeneity account for the variation in Cr contents of the samples.     

Some exact solutions for the flow of fluid through tubes with uniformly porous walls

Summary This paper considers an incompressible fluid flowing through a straight, circular tube whose walls are uniformly porous. The flow is steady and one dimensional. The loss of fluid through the wall is proportional to the mean static pressure in the tube. Several formulations of the wall shear stress are considered; these formulations were motivated by the results from Hamel's radial flow problem, boundary layer flows/and boundary layer suction profiles. For each of these formulations exact solutions for the mean axial velocity and the mean static pressure of the fluid are obtained. Sample results are plotted on graphs. For the constant wall shear stress problem, the theoretical solutions compare favorably with some experimental results.Notations A, B, D, E constant parameters - a, b constant parameters - Ai(z), Bi(z) Airy functions - Ai, Bi derivatives of Airy functions - k constant of proportionality betweenV andp - L length of pores - p,p mean static pressure - p ₀ static pressure outside the tube - p ₀ value ofp atx=0 - Q constant exponent - R inside radius of the tube - T wall shear stress - T ₀ shear parameter - t wall thickness - U free stream velocity - ,u mean axial velocity - u ₀ value ofu atx=0 - V,V mean seepage velocity through the wall - v ₀ mean seepage velocity - x,x axial distance along the tube - z transformed axial distance - z ₀ value ofz atx=0 - mean outflow angle through the wall - cos - density of the fluid - wall shear stress - dynamic viscosity of the fluid - over-bar dimensional terms - no bar nondimensional terms The National Center for Atmospheric Research is sponsored by the National Science Foundation     

Equilibrium temperatures of interstellar iron grains

Because of the relatively low number densities found in typical interstellar clouds, molecules observed there must be produced by a combination of both two-body gas-phase reactions and surface reactions. The latter type includes various catalytic reactions, such as the formation of H₂ on transition metal grains. These reactions are very temperature dependent, the grain temperature appearing in the exponential of the rate equations. Because of the small heat capacities of the grains due to their small sizes, they may be subject to considerable fluctuations in temperature. This problem is examined for iron grains and found to be minimal for sizes greater than 100 Å. Steady-state equilibrium temperatures are then calculated for a size distribution of iron particles ranging from 10³ to 10⁹ atoms per grain by a refined method of an earlier work by one of us (RGT). The results are that iron grain temperatures are significantly greater than those of dielectric grains of comparable size in the same radiation field.     

Numerical Simulation of Strongly Stratified Flow Over a Three-Dimensional Hill

A numerical study of stably stratified flow over a three-dimensional hill is presented. Large-eddy simulation is used here to examine in detail the laboratory experimental flows described in the landmark work of Hunt and Snyder about stratified flow over a hill. The flow is linearly stratified and U/Nh is varied from 0.2 to 1.0. Here N and U are the buoyancy frequency and freestream velocity respectively, and h is the height of the hill. The Reynolds number based on the hill height is varied from 365 to 2968. The characteristic flow patterns at various values of U/Nh have been obtained and they are in good agreement with earlier theoretical and experimental results. It is shown that the flow field cannot be predicted by Drazin's theory when recirculation exists at the leeside of the hill even at UNh 1. The wake structure agrees well with a two-dimensional wake assumption when U/Nh 1 but lee waves start to influence the wake structure as U/Nh increases. The dividing-streamline heights obtained in the simulation are in accordance with experimental results and Sheppard's formula. The energy loss along the dividing streamline due to friction/turbulence approximately offsets the energy gained from pressure field. When lee waves are present, linear theory always underestimates the amplitude and overestimates the wavelength of three-dimensional lee waves. The simulated variations of drag coefficients with the parameterK (=ND/ U) are qualitatively consistent with experimental data and linear theory. Here D is the depth of the tank.     

Contaminant concentrations in sport fish from San Francisco Bay, 1997

In 1997, seven sport fish species were sampled from seven popular fishing areas in San Francisco Bay. Mercury exceeded a human health screening value in 44 of 84 (52%) samples. All collected samples of leopard shark and striped bass exceeded the mercury screening value of 0.23 microg/g wet weight. PCBs exceeded the screening value in 51 of 72 (71%) samples. DDT, chlordane, and dieldrin, had lower numbers of samples above screening values: 16 of 72 (22%) for DDT, 11 of 72 (15%) for chlordanes, and 27 of 72 (37%) for dieldrin. Concentrations of PCBs and other trace organics were highest in white croaker and shiner surfperch, the two species with the highest fat content in their muscle tissue. Fish from one location, Oakland Harbor, had significantly elevated wet weight concentrations of mercury, PCBs, DDTs, and chlordanes compared to other locations. Removal of skin from white croaker fillets reduced lipid concentrations by 27-49% and concentrations of trace organics by 33-40%.     

Spatial and temporal variability of mesozooplankton and tintinnid ciliates in a seasonally hypersaline estuary

The zooplankton community of Mission Bay, San Diego, California, was monitored over two years, to study spatial and temporal patterns and the response of zooplankton species composition to environmental variation. Data were collected every two weeks from six stations and included hydrographic parameters, dissolved nutrient concentrations, and phytoplankton and zooplankton species composition. Hydrography varied seasonally, along a spatial gradient from the mouth to the back of the bay, and between the two years around the influence of rainfall. Spatially, Mission Bay could be divided into three regions during this study based on hydrography and zooplankton species composition. Zooplankton species composition followed a predictable seasonal progression, with different groups of species being characteristic to particular times of the year. Variability in zooplankton species composition was also evident between years, as certain species were more common in one or the other year of the study. Spatial patterns were more consistent than temporal ones, and related to distance from the mouth of the bay during much of the year and distance from freshwater inlets during the relatively short rainy season. Multivariate analysis revealed that variation in zooplankton species composition was best related to measured abiotic factors (temperature, salinity, rainfall, and tidal velocity).